RutheniumII Complexes bearing Fused Polycyclic Ligands: From Fundamental Aspects to Potential Applications

Troian-Gautier, Ludovic;Moucheron, Cécile
(2014) Molecules — Vol. 19, n° 4, p. 5028-5087 (2014)

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Abstract
In this review, we first discuss the photophysics reported in the literature for mononuclear ruthenium complexes bearing ligands with extended aromaticity such as dipyrido[3,2-a:2',3'-c]phenazine (DPPZ), tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]-phenazine (TPPHZ), tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]acridine (TPAC), 1,10-phenanthrolino[5,6-b]1,4,5,8,9,12-hexaazatriphenylene (PHEHAT) 9,11,20,22-tetraaza- tetrapyrido[3,2-a:2',3'-c:3'',2''-l:2''',3'''-n]pentacene (TATPP), etc. Photophysical properties of binuclear and polynuclear complexes based on these extended ligands are then reported. We finally develop the use of binuclear complexes with extended π-systems for applications such as photocatalysis.
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Troian-Gautier, L., & Moucheron, C. (2014). RutheniumII Complexes bearing Fused Polycyclic Ligands: From Fundamental Aspects to Potential Applications. Molecules, 19(4), 5028-5087. https://doi.org/10.3390/molecules19045028 (Original work published 2014)