Chromate-mediated one-step quantitative transformation of PW 12 into P 2W 20 polyoxometalates

Bajpe, S.R.; Breynaert, E.; Robeyns, Koen; Houthoofd, K.; Absillis, G.; Mustafa, D.; Parac-Vogt, T.N.; Maes, A.; Martens, J.A.; Kirschhock, C.E.A.

doi:10.1002/ejic.201200440

Chromate-mediated one-step quantitative transformation of PW 12 into P 2W 20 polyoxometalates

Bajpe, S.R.

;

Breynaert, E.

;

Robeyns, Koen

;

Houthoofd, K.

;

Kirschhock, C.E.A.

;et.al.

(2012) European Journal of Inorganic Chemistry — Vol. 2012, n° 24, p. 3852-3858 (2012)

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Authors

Bajpe, S.R.
Author
Breynaert, E.
Author
Robeyns, KoenUCLouvain
Author
Houthoofd, K.
Author
Kirschhock, C.E.A.
Author

Abstract

The addition of H 3PW 12O 40 to an aqueous solution of K 2CrO 4 led to the hydrolysis of [PW 12O 40] 3- with its quantitative conversion into K 13[KP 2W 20O 72]. K 13[KP 2W 20O 72] in these chromate-containing solutions was characterized by 183W and 31P NMR, EXAFS, SAXS, and EPR spectroscopy. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Affiliations

UCLouvainSST/IMCN/MOST - Molecular Chemistry, Materials and Catalysis

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Bajpe, S. R., Breynaert, E., Robeyns, K., Houthoofd, K., Absillis, G., Mustafa, D., Parac-Vogt, T. N., Maes, A., Martens, J. A., & Kirschhock, C. E. A. (2012). Chromate-mediated one-step quantitative transformation of PW 12 into P 2W 20 polyoxometalates. European Journal of Inorganic Chemistry, 2012(24), 3852-3858. https://doi.org/10.1002/ejic.201200440 (Original work published 2012)