Anodization behaviour of friction stir processed aluminium surface composites

Shabadi, Rajashekhara;Gudla, Visweswara;Rajan, Ambat;Jensen, Flemming;Simar, Aude
(2016) Thermec 2016 — Location: Graz, Austria (29.May.2016)

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Authors
  • Shabadi, RajashekharaUniversité Lille 1, France
    Author
  • Gudla, VisweswaraTechnical University of Denmark, Lyngby, Denmark
    Author
  • Rajan, AmbatTechnical University of Denmark, Lyngby, Denmark
    Author
  • Jensen, FlemmingTechnical University of Denmark, Lyngby, Denmark
    Author
  • Simar, AudeUCLouvain
    Author
Abstract
Multiple-pass friction stir processing (FSP) was employed to impregnate TiO2 (rutile) powders into the surface of an Aluminium alloy. The surface composites of Al-TiO2 were then anodized in a sulphuric acid electrolyte. The effect of anodizing parameters on the resulting optical appearance was studied. Microstructural and morphological characterization was performed using scanning (SEM) and transmission electron microscopy (TEM), and X-ray diffraction (XRD). The surface appearance was analysed using an integrating sphere-spectrometer setup which measures the diffuse and total reflectance of light from the surface. Compared to samples without TiO2, surface appearance after anodizing of samples with TiO2 changed from dark to greyish white upon increasing the anodizing voltage. This is attributed to the localized microstructural and morphological differences around the TiO2 particles incorporated into the anodic alumina matrix. The TiO2 particles in the FSP zone were partially or completely amorphized during the anodizing process, and also electrochemically shadowed the anodizing of underlying Al matrix.
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Citations

Shabadi, R., Gudla, V., Rajan, A., Jensen, F., & Simar, A. (2016). Anodization behaviour of friction stir processed aluminium surface composites. Thermec 2016, Graz, Austria. https://hdl.handle.net/2078.5/44981