Hydrogen Photoevolution from a Green-Absorbing Iridium(III)-Cobalt(III) Dyad

Jacques, Alexandre;Schott, O.;Robeyns, Koen;Hanan, G.S.;Elias, Benjamin
(2016) European Journal of Inorganic Chemistry — Vol. 2016, n° 12, p. 1779-1783 (2016)

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Abstract
A bis-cyclometaling ligand afforded a novel IrIII–CoIII dinuclear complex with vectorial electron transfer that evolved hydrogen gas upon yellow-light irradiation. The supramolecular photosystem provided increased stability during photocatalysis with respect to that of classic bidentate systems.
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Jacques, A., Schott, O., Robeyns, K., Hanan, G. S., & Elias, B. (2016). Hydrogen Photoevolution from a Green-Absorbing Iridium(III)-Cobalt(III) Dyad. European Journal of Inorganic Chemistry, 2016(12), 1779-1783. https://doi.org/10.1002/ejic.201501467 (Original work published 2016)