Vinyl T-butyl Sulfoxides As Trifluoroacetoxy Sulfenylating Agents Towards Olefins

Brichard, MH.;Janousek, Z.;Viehe, HG.
(1993) Journal fuer Praktische Chemie. Chemiker-Zeitung — Vol. 335, n° 2, p. 143-146 (1993)

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  • Brichard, MH.
    Author
  • Janousek, Z.
    Author
  • Viehe, HG.
    Author
Abstract
Acceptor substituted vinylic t-butyl sulfoxides behave in acidic medium as formal vinylthiyl cations. These electrophilic species add to olefins, hexyne and allene to form beta-trifluoroacetoxy-sulfenylation products 9.
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Brichard, MH., Janousek, Z., & Viehe, HG. (1993). Vinyl T-butyl Sulfoxides As Trifluoroacetoxy Sulfenylating Agents Towards Olefins. Journal fuer Praktische Chemie. Chemiker-Zeitung, 335(2), 143-146. https://doi.org/10.1002/prac.19933350205 (Original work published 1993)