Synthesis and characterization of outer coordination sphere complexes: [LH+](2)[SnCl62-], [LH+](2)[Me4Sn2Cl62-] and [LH+][Ph2SnCl3-](LH+ = protonated 2-methoxy-1-[(4-chlorophenylimino)methyl]naphthalene). Crystal structure of 2-methoxy-1-[(4-chlorophenylimino)-methyl]naphthalenium trichlorodiphenylstannate(IV), [LH+][Ph2SnCl3-], derived from diphenyltin dichloride and 2-methoxy-1-[(4-chlorophenylimino)-methyl]naphthalene

Yeap, GY.;Declercq, Jean-Paul;Ng, AC;Teoh, SG.;Teo, SB.
(1999) Journal of Coordination Chemistry — Vol. 48, n° 1, p. 63-72 (1999)

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  • Yeap, GY.
    Author
  • Declercq, Jean-PaulUCLouvain
    Author
  • Ng, AC
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  • Teoh, SG.
    Author
  • Teo, SB.
    Author
Abstract
The reactions of SnCl4, Me2SnCl2 and Ph2SnCl2 with the Schiff base (L) 2-methoxy-1-[(4-chlorophenylimino)methyl]naphthalene result in the formation of tin(IV) anionic complexes. Ph2SnCl2 reacts with the Schiff base in dichloromethane to form the complex salt [LH+][Ph2SnCl3-] (LH+ = protonated L). X-ray structural analysis has been carried out on a single crystal of [LH+][Ph2SnCl3-]. The reactions of SnCl4 and Me2SnCl2 with the Schiff base form the complexes [LH+](2)[SnCl62-] and [LH+](2)[Me4Sn2Cl62-], respectively. All complex salts were characterized by elemental analysis and spectroscopic methods (IR and H-1 NMR).
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Yeap, GY., Declercq, J.-P., Ng, A., Teoh, SG., & Teo, SB. (1999). Synthesis and characterization of outer coordination sphere complexes: [LH+](2)[SnCl62-], [LH+](2)[Me4Sn2Cl62-] and [LH+][Ph2SnCl3-](LH+ = protonated 2-methoxy-1-[(4-chlorophenylimino)methyl]naphthalene). Crystal structure of 2-methoxy-1-[(4-chlorophenylimino)-methyl]naphthalenium trichlorodiphenylstannate(IV), [LH+][Ph2SnCl3-], derived from diphenyltin dichloride and 2-methoxy-1-[(4-chlorophenylimino)-methyl]naphthalene. Journal of Coordination Chemistry, 48(1), 63-72. https://doi.org/10.1080/00958979908024364 (Original work published 1999)