Molecular-mass Determination and Dilute-solution Properties of Polyether From Bisphenols and 4,4'-dichlorodiphenyl Sulfone

Charlier, Y.;Godard, Pierre;Daoust, Daniel;Strazielle, C.
(1994) Macromolecules — Vol. 27, n° 13, p. 3604-3610 (1994)

Files

No attached file found for this publication.

Details

Authors
  • Charlier, Y.
    Author
  • Godard, PierreUCLouvain
    Author
  • Daoust, DanielUCLouvain
    Author
  • Strazielle, C.
    Author
Abstract
Molecular characterization of PES by light scattering, viscometry, and size exclusion chromatography (SEC) is described. A Mark-Houwink-Sakurada relationship in NMP + 0.1 M LiBr is established. From specific and universal calibrations, absolute molecular masses of PES are obtained by SEC. Number average molecular masses from SEC and H-1 NMR are compared. The study of PES conformation in dilute solution reveals a high flexibility of the PES chain in a good solvent. The sigma factor is close to 1, and the Kuhn statistical element contains approximately six repeat units.
Affiliations

Citations

  • APA
  • Chicago
  • FWB

Charlier, Y., Godard, P., Daoust, D., & Strazielle, C. (1994). Molecular-mass Determination and Dilute-solution Properties of Polyether From Bisphenols and 4,4′-dichlorodiphenyl Sulfone. Macromolecules, 27(13), 3604-3610. https://doi.org/10.1021/ma00091a023 (Original work published 1994)