Preparation of IL-loaded microreactors based on polyelectrolyte microcapsules

SOURON, Elodie;Gaumont, Annie-Claude;Glinel, Karine;DEZ, Isabelle
(2016) French-Ukrainian Journal of Chemistry — Vol. 04, n° 01, p. 95 (2016)

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Authors
  • SOURON, ElodieNormandie Université, LCMT, ENSICAEN, UNICAEN, CNRS, France
    Author
  • Gaumont, Annie-ClaudeNormandie Université, LCMT, ENSICAEN, UNICAEN, CNRS, France
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  • Glinel, Karineorcid-logoUCLouvain
    Author
  • DEZ, IsabelleNormandie Université, LCMT, ENSICAEN, UNICAEN, CNRS, France
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Abstract
Encapsulation of ionic liquids (ILs) in crosslinked polyelectrolyte microcapsules, made via layer-by-layer assembly (LbL) was successfully conducted. Two different ILs were studied: 1-butyl-3-methylimidazolium tetrafluoroborate [Bmim]BF4 and 1-butyl-3-methylimidazolium hexafluorophosphate [Bmim]PF6. The polyelectrolyte microcapsules were successfully used as microcages for the synthesis of poly(methylmethacrylate) (PMMA), a non water-soluble polymer, in IL medium. Finally, the behaviour of the IL-loaded microreactors in polar and apolar solvents was evaluated. The strategies described in this study offer new routes for the preparation of microreactors incorporating IL which are of interest for many applications in the field of organic synthesis, catalysis and adsorption of active substances.
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SOURON, E., Gaumont, A.-C., Glinel, K., & DEZ, I. (2016). Preparation of IL-loaded microreactors based on polyelectrolyte microcapsules. French-Ukrainian Journal of Chemistry, 04(01), 95. https://doi.org/10.17721/fujcV4I1P95-108 (Original work published 2016)