Rheotens mastercurves and elongational viscosity of polymer melts

Wagner, MH;Collignon, Benoit;Verbeke, J
(1996) Rheologica Acta : an international journal of rheology — Vol. 35, n° 2, p. 117-126 (1996)

Files

pdfdocument.pdf
  • Restricted Access
  • Adobe PDF
  • 724.95 KB

Details

Authors
  • Wagner, MH
    Author
  • Collignon, BenoitUCLouvain
    Author
  • Verbeke, J
    Author
Abstract
In a Rheotens experiment, the tensile force needed for elongation of an extruded filament is measured as a function of the draw ratio. For thermo-rheologically simple polymer melts, the existence of Rheotens-mastercurves was proved by Wagner, Schulze, and Gottfert (1995). Rheotens-mastercurves are invariant with respect to changes in melt temperature and changes in the average molar mass. By use of purely viscous models, we convert Rheotens-mastercurves of a branched and a linear polyethylene melt to elongational viscosity as a function of strain rate. The resulting elongational viscosity from constant force extension experiments is found to be in general agreement with what is expected as steady-state viscosity of polyethylene melts measured in either constant strain-rate or constant stress mode.
Affiliations

Citations

Wagner, M., Collignon, B., & Verbeke, J. (1996). Rheotens mastercurves and elongational viscosity of polymer melts. Rheologica Acta : an international journal of rheology, 35(2), 117-126. https://doi.org/10.1007/BF00396038 (Original work published 1996)