From a mononuclear NiII precursor to antiferromagnetically coupled trinuclear double-stranded helicates

Safin, D.A.;Babashkina, M.G.;Robeyns, Koen;Rouzières, M.;Garcia, Yann;et.al.
(2013) Dalton Transactions — Vol. 42, n° 47, p. 16470-16473 (2013)

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Authors
  • Safin, D.A.UCLouvain
    Author
  • Babashkina, M.G.UCLouvain
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  • Robeyns, KoenUCLouvain
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  • Rouzières, M.autre
    Author
  • Garcia, Yannorcid-logoUCLouvain
    Author
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Abstract
Reaction of the mononuclear NiII complex [Ni{2-Py(6-NH 2)NHC(S)NP(S)(OiPr)2}2] with different salicylaldehydes leads to new antiferromagnetically coupled trinuclear double-stranded helicates 1-3, where NiII metal ions are coordinated by two bis-anionic thiourea ligands and two deprotonated molecules of the corresponding aldehyde. © 2013 The Royal Society of Chemistry.
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Safin, D. A., Babashkina, M. G., Robeyns, K., Rouzières, M., Clérac, R., & Garcia, Y. (2013). From a mononuclear NiII precursor to antiferromagnetically coupled trinuclear double-stranded helicates. Dalton Transactions, 42(47), 16470-16473. https://doi.org/10.1039/c3dt52387j (Original work published 2013)