High-pressure polymorphism as a step towards destabilization of LiBH 4

Filinchuk, Yaroslav;Chernyshov, D.;Nevidomskyy, A.;Dmitriev, V.
(2008) Angewandte Chemie (International Edition) — Vol. 47, n° 3, p. 529-532 (2008)

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Abstract
Performing under pressure: The BH4 group in the high-pressure modification of LiBH4 has an unprecedented square-planar coordination by four Li atoms (see picture). This structure exhibits a strikingly short H⋯H contact between adjacent BH4 anions and thus may show completely different hydrogen-storage properties if stabilized by chemical substitution at ambient pressure. (Figure Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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  • ESRF, Grenoble (France)Chimie

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Filinchuk, Y., Chernyshov, D., Nevidomskyy, A., & Dmitriev, V. (2008). High-pressure polymorphism as a step towards destabilization of LiBH 4. Angewandte Chemie (International Edition), 47(3), 529-532. https://doi.org/10.1002/anie.200704777 (Original work published 2008)