Stereoselective synthesis of methyl monate C.

van Innis, Livia;Plancher, Jean Marc;Marko, Istvan
(2006) Organic Letters —

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Authors
  • van Innis, Livia
    Author
  • Plancher, Jean Marc
    Author
  • Marko, IstvanUCLouvain
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Abstract
[Structure: see text] The stereoselective synthesis of methyl monate C 2 is described using as a key step an ene-intramolecular modified Sakurai cyclization (IMSC) reaction to prepare tetrahydropyran 5. An asymmetric allylic alkylation, followed by a cross-metathesis, enables the insertion of the right-hand side chain.
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van Innis, L., Plancher, J. M., & Marko, I. (2006). Stereoselective synthesis of methyl monate C. Organic Letters. https://doi.org/10.1021/ol0625785