Snr 2(O 2phph) 2 (R=Me, Bu), Snbu 3o 2phph, Me 4NO 2PHPh.2snph 3cl and Cy 2NH 2SnPh 2(O 2phph) 3: Synthesis and spectroscopic studies

De Barros, Dinora;Diop, Libasse;Mahieu, Bernard
(2010) Main Group Metal Chemistry — Vol. 33, n° 1-2, p. 83-89 (2010)

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  • De Barros, Dinora
    Author
  • Diop, Libasse
    Author
  • Mahieu, BernardUCLouvain
    Author
Abstract
Five phenylhydrophosphinato organotin(IV) derivatives and adducts have been synthesized and studied by infrared and Mössbauer techniques. The structures suggested on the basis of spectroscopic data are of discrete, infinite or oligomeric types, the phenylhydrophosphinate anion behaving as a bridging bidentate or a monodentate ligand, the environment around the tin centre being trigonal bipyramidal or octahedral.
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De Barros, D., Diop, L., & Mahieu, B. (2010). Snr 2(O 2phph) 2 (R=Me, Bu), Snbu 3o 2phph, Me 4NO 2PHPh.2snph 3cl and Cy 2NH 2SnPh 2(O 2phph) 3: Synthesis and spectroscopic studies. Main Group Metal Chemistry, 33(1-2), 83-89. https://hdl.handle.net/2078.5/91397 (Original work published 2010)