Ene-type Addition of Alkenes To Phenyl Vinylsulfoxide

Brichard, MH.;Janousek, Z.;Merenyi, R.;Viehe, HG.
(1992) Tetrahedron Letters — Vol. 33, n° 18, p. 2511-2514 (1992)

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Authors
  • Brichard, MH.
    Author
  • Janousek, Z.
    Author
  • Merenyi, R.
    Author
  • Viehe, HG.
    Author
Abstract
Phenyl vinylsulfoxide reacts under acylating conditions (TFA, TFAA) with isobutene to give double 'ene" alpha,beta-adduct Propene and other alkenes examined afford a beta-"ene" alkylation accompanied by trifluoroacetoxylation at the same carbon atom.
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Citations

Brichard, MH., Janousek, Z., Merenyi, R., & Viehe, HG. (1992). Ene-type Addition of Alkenes To Phenyl Vinylsulfoxide. Tetrahedron Letters, 33(18), 2511-2514. https://doi.org/10.1016/S0040-4039(00)92228-7 (Original work published 1992)