NH 2-MIL-53(Al): A high-contrast reversible solid-state nonlinear optical switch

Serra-Crespo, P.;Van Der Veen, M.A.;Gobechiya, E.;Houthoofd, K.;Gascon, J.;et.al.
(2012) Journal of the American chemical society — Vol. 134, n° 20, p. 8314-8317 (2012)

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Authors
  • Serra-Crespo, P.Delft University of Technology (The Netherland)
    Author
  • Van Der Veen, M.A.University of Leuven (KUL)
    Author
  • Gobechiya, E.University of Leuven (KUL)
    Author
  • Houthoofd, K.University of Leuven (KUL)
    Author
  • Filinchuk, YaroslavUCLouvain
    Author
  • Gascon, J.Delft University of Technology (The Netherlands)
    Author
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Abstract
The metal-organic framework NH 2-MIL-53(Al) is the first solid-state material displaying nonlinear optical switching due to a conformational change upon breathing. A switching contrast of at least 38 was observed. This transition originates in the restrained linker mobility in the very narrow pore configuration. © 2012 American Chemical Society.
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Serra-Crespo, P., Van Der Veen, M. A., Gobechiya, E., Houthoofd, K., Filinchuk, Y., Kirschhock, C. E. A., Martens, J. A., Sels, B. F., De Vos, D. E., Kapteijn, F., & Gascon, J. (2012). NH 2-MIL-53(Al): A high-contrast reversible solid-state nonlinear optical switch. Journal of the American chemical society, 134(20), 8314-8317. https://doi.org/10.1021/ja300655f (Original work published 2012)