Selective manganese-mediated transformations using the combination: KMnO4/Me(3)SiCl

Marko, Istvan;Richardson, PR;Bailey, M.;Maguire, AR;Coughlan, N
(1997) Tetrahedron Letters — Vol. 38, n° 13, p. 2339-2342 (1997)

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Authors
  • Marko, IstvanUCLouvain
    Author
  • Richardson, PR
    Author
  • Bailey, M.
    Author
  • Maguire, AR
    Author
  • Coughlan, N
    Author
Abstract
A novel manganese reagent, generated from KMnO4 and Me(3)SiCl, in the presence of a quaternary ammonium salt, is shown to smoothly dichlorinate alkenes, open epoxides and chemoselectively oxidise sulfides to sulfoxides. (C) 1997 Elsevier Science Ltd.
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Marko, I., Richardson, P., Bailey, M., Maguire, A., & Coughlan, N. (1997). Selective manganese-mediated transformations using the combination: KMnO4/Me(3)SiCl. Tetrahedron Letters, 38(13), 2339-2342. https://doi.org/10.1016/S0040-4039(97)00309-2 (Original work published 1997)