Synthesis, Structural Characterization, and Hydrogen Release of Al-Based Amidoboranes Derived from MAlH4 (Li, Na)-BH3NH2CH2CH2NH2BH3
(2025) Molecules : a journal of synthetic organic and natural product chemistry — Vol. 30, n° 7, p. 1559 (2025)
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Devillers, Michel 
- Abstract
- Over the past two decades, the high hydrogen content and favorable dehydrogenation conditions of multi-metallic amidoboranes have gained significant attention for their potential in hydrogen storage. Among them, Al-based complex hydrides have shown promise because of their high polarizing power, light weight, and abundant natural presence. In this work, we successfully synthesized two novel tetrahedrally coordinated Al-based amidoboranes, namely, Li[Al(BH3NHCH2CH2NHBH3)2] and Na(THF)[Al(BH3NHCH2CH2NHBH3)2], using BH3NH2CH2CH2NH2BH3 (EDAB) as a precursor. The structure of Na(THF)[Al(BH3NHCH2CH2NHBH3)2] was determined through modeling based on synchrotron powder X-ray diffraction. Additionally, the formation of the Al-N bond in Li[Al(BH3NHCH2CH2NHBH3)2] and Na(THF)[Al(BH3NHCH2CH2NHBH3)2] was confirmed with IR spectra. Na(THF)[Al(BH3NHCH2CH2NHBH3)2] is more stable in air than Li[Al(BH3NHCH2CH2NHBH3)2]. Importantly, thermal gravimetric analysis and mass spectroscopic characterization confirmed that both compounds release hydrogen without the presence of ammonia, diborane, or ethylenediamine. Our work represents the first example of Al-based amidoboranes with chelation coordination geometry, which provides an essential foundation for understanding the relationship of complex multi-metallic amidoboranes in terms of synthesis, structure, and properties.
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Citations
Zhang, T., Xiao Li, Hai-Wen Li, Devillers, M., & Filinchuk, Y. (2025). Synthesis, Structural Characterization, and Hydrogen Release of Al-Based Amidoboranes Derived from MAlH4 (Li, Na)-BH3NH2CH2CH2NH2BH3. Molecules : a journal of synthetic organic and natural product chemistry, 30(7), 1559. https://doi.org/10.3390/molecules30071559 (Original work published 2025)