Halogen anion-induced formation of [(PdLX)2](X = Cl-, Br-, I-) vs. [PdL2] (L = [6-MeO(O)CC6H4NHC(S)NP(S)(OiPr)2]-): Reversible photoinduced cis/ trans isomerization of [PdL 2]
(2012) Dalton Transactions — Vol. 41, n° 15, p. 4324-4327 (2012)
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- Reaction of the potassium salt of N-thiophosphorylated thiourea 6-MeO(O)CC 6H 4NHC(S)NHP(S)(OiPr) 2 (HL) with PdX 2 (X = Cl -, Br -, I -) leads to the dark red binuclear complexes [(PdLX) 2], while the same reaction with PdY 2 (Y = NO 3 -, CN -, CH 3COO -) leads to the light red mononuclear complex [PdL 2]. [PdL 2] exhibits reversible photoinduced cis-isomerization upon irradiation at 365 or 450 nm, reverting back to the trans-isomer in darkness or upon irradiation at 546 nm. © 2012 The Royal Society of Chemistry.
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Safin, D., Babashkina, M. G., Robeyns, K., & Garcia, Y. (2012). Halogen anion-induced formation of [(PdLX)2](X = Cl-, Br-, I-) vs. [PdL2] (L = [6-MeO(O)CC6H4NHC(S)NP(S)(OiPr)2]-): Reversible photoinduced cis/ trans isomerization of [PdL 2]. Dalton Transactions, 41(15), 4324-4327. https://doi.org/10.1039/c2dt12466a (Original work published 2012)