The Intramolecular Silyl-modified Sakurai (isms) Reaction - Stereoselective Preparation of Tri-substituted and Tetra-substituted Tetrahydropyrans

Marko, Istvan;Bayston, DJ.
(1993) Tetrahedron Letters — Vol. 34, n° 41, p. 6595-6598 (1993)

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Authors
  • Marko, IstvanUCLouvain
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  • Bayston, DJ.
    Author
Abstract
The ISMS condensation of allylsilane 4 does not follow the expected pathway but rather leads to an efficient synthesis of trisubstituted and tetrasubstituted tetrahydropyran derivatives.
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Marko, I., & Bayston, DJ. (1993). The Intramolecular Silyl-modified Sakurai (isms) Reaction - Stereoselective Preparation of Tri-substituted and Tetra-substituted Tetrahydropyrans. Tetrahedron Letters, 34(41), 6595-6598. https://doi.org/10.1016/0040-4039(93)88114-X (Original work published 1993)