Synthesis of poly(methylphenylsilane) using [K+K-] solutions in THF

Lacavegoffin, B.;Hevesi, L.;Devaux, Jacques
(1996) Chemical Communications — n° 6, p. 765-766 (1996)

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  • Lacavegoffin, B.
    Author
  • Hevesi, L.
    Author
  • Devaux, JacquesUCLouvain
    Author
Abstract
[K+/K-] in THF solution allows for the low-temperature (-65 to -75 degrees C) synthesis of poly(methylphenylsilane) in 35-45% yield from dichloromethylphenylsilane under homogeneous conditions.
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Lacavegoffin, B., Hevesi, L., & Devaux, J. (1996). Synthesis of poly(methylphenylsilane) using [K+K-] solutions in THF. Chemical Communications, 6, 765-766. https://doi.org/10.1039/cc9960000765 (Original work published 1996)