Isolated [Ni2H7]7- and [Ni 4H12]12- ions in La2MgNi 2H8

Chotard, J.-N.;Filinchuk, Yaroslav;Revaz, B.;Yvon, K.
(2006) Angewandte Chemie (International Edition) — Vol. 45, n° 46, p. 7770-7773 (2006)

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Abstract
Isolated and complex: La2MgNi2H8 contains isolated dinuclear [Ni2H7]7- and tetranuclear [Ni4H12]12- anions (see picture). These are the first polynuclear solid-state nickel hydride complexes. Their formation upon hydrogenation of the intermetallic compound La2MgNi2 is associated with a metal-insulator transition. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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  • ESRF, Grenoble (France)Chimie

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Chotard, J.-N., Filinchuk, Y., Revaz, B., & Yvon, K. (2006). Isolated [Ni2H7]7- and [Ni 4H12]12- ions in La2MgNi 2H8. Angewandte Chemie (International Edition), 45(46), 7770-7773. https://doi.org/10.1002/anie.200603651 (Original work published 2006)