Mossbauer Study On the Gamma-radiolysis of Anhydrous Cesium Tris (oxalato) Ferrate(iii)

Ladrière, Jean;Senterre, V.;Apers, Désiré
(1992) INTERNATIONAL CONF ON THE APPLICATIONS OF THE MOSSBAUER EFFECT ( ICAME 91 ) — Location: NANJING(Peoples R China) (16.September.1991)

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Authors
  • Ladrière, JeanUCLouvain
    Author
  • Senterre, V.
    Author
  • Apers, DésiréUCLouvain
    Author
Abstract
The final product of the gamma radiolysis of anhydrous cesium tris(oxalato) ferrate(III) has been identified by Mossbauer spectroscopy as Cs2Fe(ox)2. The radiolytic decomposition proceeds as a first-order process due to the original compound depletion and to the radiolytic stability of the ferrous compound. Lamb-Mossbauer factors measurements indicate that the recoilless fractions of the iron species arc practically unaffected by thc radiolysis.
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Ladrière, J., Senterre, V., & Apers, D. (1992). Mossbauer Study On the Gamma-radiolysis of Anhydrous Cesium Tris (oxalato) Ferrate(iii). Hyperfine Interactions, 70(1-4), 917-920. https://doi.org/10.1007/BF02397477 (Original work published 1992)