Efficient enantioselective hydrosilylation of ketones catalyzed by air stable copper fluoride-phosphine complexes.
(2001) Organic Letters — Vol. 3, n° 25, p. 4111-4113 (2001)
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- Abstract
- [reaction: see text] Copper(II) fluoride-chiral diphosphine systems catalyze the hydrosilylation of several ketones with moderate to excellent enantioselectivities. An oxygen acceleration effect was observed and led to a practical protocol with low catalyst loading.
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Citations
Sirol, S., Courmarcel, J., Mostefai, N., & Riant, O. (2001). Efficient enantioselective hydrosilylation of ketones catalyzed by air stable copper fluoride-phosphine complexes. Organic Letters, 3(25), 4111-4113. https://doi.org/10.1021/ol0169170 (Original work published 2001)