Crystal structure of bis(azido-κN)bis(quinolin-8-amine-κ2N,N′)iron(II)
(2016) Acta Crystallographica Section E: Crystallographic Communications — Vol. 72, n° 10, p. 1488-1491 (2016)
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- Abstract
- The search for new molecular materials with interesting magnetic properties using the pseudohalide azide ion and quinolin-8-amine (aqin, C9H8N2) as a chelating ligand, led to the synthesis and structure determination of the title complex, [Fe(N3)2(C9H8N2)2]. The complex shows an octahedral geometry, with the FeII atom surrounded by six N atoms; the two N3- anions coordinate in a cis configuration, while the remaining N atoms originate from the two quinolin-8- amine ligands with the quinoline N atoms lying on opposite sides of the Fe atom. The crystal packing is dominated by layers of hydrophilic and aromatic regions parallel to the ac plane, stabilized by a two-dimensional hydrogen-bonded network and pi–pi stacking.
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Citations
Setifi, F., Moon, D., Koen, R., Setifi, Z., Lamsayah, M., & Touzani, R. (2016). Crystal structure of bis(azido-κN)bis(quinolin-8-amine-κ2N,N′)iron(II). Acta Crystallographica Section E: Crystallographic Communications, 72(10), 1488-1491. https://doi.org/10.1107/s2056989016014808 (Original work published 2016)